By William Pryor (Eds.)

ISBN-10: 0125665024

ISBN-13: 9780125665025

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Kosower pathway is that the geometric requirements for hydrogen transfer are less strict than would be expected for the tightly bound transition state for hydride transfer. At least, that surmise might explain why the one-electron pathway could have evolved. Westheimer [89] has already explained that twoelectron reactions are alive and well and flourishing. However, if pyridine nucleotides can be proved to catalyze enzymatic reactions by one-electron transfer reactions, investigation of the evolution of such systems would be­ come important.

W. Moore, G. M. Muha, and Κ. H. Berry, / . Org. Chem. 29, 2175 (1964).

L. Cotter, / . Amer. Chem. Soc. 86, 5524 (1964). P. H. Kasai and D. , / . Amer. Chem. Soc. 92, 6085 (1970) ; 94, 720 (1972). R. S. Mulliken, / . Amer. Chem. Soc. 74, 811 (1952). Ε. M. Kosower and P. E. , / . Amer. Chem. Soc. 78, 3493 (1956). Ε. M. Kosower, / . Amer. Chem. Soc. 78, 3497 (1956). Ε. M. Kosower and L. Lindqvist, Tetrahedron Lett. p. 4481 (1965). C. S. Johnson, Jr. and H. S. Gutowsky, / . Chem. Phys. 39, 58 (1963). A. S. Hopkins, A. Ledwith, and M. F. Stam, Chem. Commun, p. 494 (1970).

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Free Radicals in Biology by William Pryor (Eds.)


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