By J.S. Brimacombe
Carbohydrate Chemistry presents evaluate assurance of all guides proper to the chemistry of monosaccharides and oligosaccharides in a given 12 months. the volume of study during this box showing within the natural chemical literature is expanding a result of more suitable significance of the topic, in particular in parts of medicinal chemistry and biology. In no a part of the sector is that this extra obvious than within the synthesis of oligosaccharides required through scientists operating in glycobiology. Clycomedicinal chemistry and its reliance on carbohydrate synthesis is now rather well proven, for instance, by way of the training of particular carbohydrate- dependent antigens, specially cancer-specific oligosaccharides and glycoconjugates. insurance of themes resembling nucleosides, amino-sugars, alditols and cyclitols additionally covers a lot study of relevance to organic and medicinal chemistry. each one quantity of the sequence brings jointly references to all released paintings in given components of the topic and serves as a entire database for the lively examine chemist. professional Periodical stories offer systematic and distinctive assessment insurance in significant components of chemical examine. Compiled through groups of major specialists within the proper topic parts, the sequence creates a special provider for the lively examine chemist, with ordinary, in-depth money owed of development particularly fields of chemistry. topic assurance inside of various volumes of a given name is identical and e-book is on an annual or biennial foundation.
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1974, 37, 75. K. L. , 1973, 31, 410. K. L. Matta, E. A. Z. Johnson, and J. J. , 1974, 32, 418. K. L. Matta, E. A. Z. Johnson, and J. J. , 1974, 32, 396. -R. Pougny and P. , 1974, 38, 161. S. Koto, K. Yago, S. Zen, and S . Omura, Bull. Chem. SOC. Japan, 1973, 46, 3800. N. K. Kochetkov, B. A. Dmitriev, 0. S. Chizhov, E. M. Klimov, N. N. Malysheva, V. I. Torgov, Ya. A. Chernyak, and N. E. Bairamova, Izuest. Akad. , Ser. , 1974, 1386. K. Takiura, M. Yamamoto, Y. Miyaji, H. Takai, S. Honda, and H.
Dietzsch, and G. Fischer, Pharmazie, 1974, 29, 95. g. (30)and (31)] have been prepared for subsequent attachment to solid 134 The photolysis of glycosyl phenyl sulphones is noted immediately below. C-GIycosides The photolytic decomposition of a- and /3-D-glucopyranosyl phenyl sulphone acetates in benzene yielded a number of products, including those illustrated in Scheme 14. ~~~ Russian workers have reported the preparation of the diastereoisomeric C-glycosyl-oxirans (32) (Scheme 15) 137, 137a and (33),137aboth of which inhibited sweet-almond j3-glucosidase.
M. Anisuzzaman, and J. C. , 1973, 31, 237. J. M. Ballard, L. Hough, and A. C. , 1974, 34, 184. L. Brewer, S. David, and A. , 1974, 36, 188. P. KoviE and R. , 1974, 36, 379. J. F. Batey and J. R. , 1974, 38, 316. Z . , 1974, 38, 117. R. S. Bhatt, L. Hough, and A. C. , 1974, 32, C4. New ~ ~ ~ monoesters of indole-3-acetic acid and D-glucose, in which the hexose is esterified at 0-2, -3, -4,and -6, have been isolated from sweet-corn kernels of Zea mays,236and l-O-(indole-3-acety~)-~-~-glucopyranose labelled with 14C in the carboxy-group has been synthesized by standard N-(Tri-0-methylgalloy1)- and N-(tri-0-benzylgalloy1)-imidazoles have been used to prepare fully 237 and partially 238 acylated derivatives of methyl a-D-glucopyranoside and its 6-0-trityl ether; thus, partial acylation gave the 6-mono-, 2,6-di-, and 2,3,6-tri-substituted derivatives of the former and the 2-mono- and 2,3-di-substituted derivatives of the latter.
Carbohydrate Chemistry: v. 8 by J.S. Brimacombe