By Colin D. Hubbard Rudi Van Eldik

ISBN-10: 0120236540

ISBN-13: 9780120236541

The Advances in Inorganic Chemistry sequence provides well timed and informative summaries of the present growth in numerous topic parts inside of inorganic chemistry starting from bio-inorganic to strong country reports. This acclaimed serial gains experiences written by way of specialists within the sector and is an vital connection with complicated researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is totally referenced. This, the 54th quantity within the sequence maintains this custom delivering entire studies via prime specialists within the box with the point of interest on inorganic and bioinorganic response mechanisms. * the most recent quantity during this hugely winning sequence is devoted to inorganic and bioinorganic response mechanisms* accomplished reports written by way of best specialists within the box

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DUNAND et al.

C RRSS form of the macrocycle. d Five coordinate RSRS form of macrocycle. molecules on [Ru(MeCN)6]2+ by a (Z6 -C6H6) or by a (Z5 -C5H5) accelerates the exchange of the remaining three MeCN by 6 or 11 orders of magnitude, respectively. Replacing three water molecules however on the corresponding hexa-aqua complex by (Z6 -C6H6) increases the exchange rate of the remaining H2O molecules only by a factor of 640. Substituting one or two water molecules by small monodentate ligands allowed a study of the in£uence of axial and equatorial water molecules on the lability.

Activation volumes on complexes of the form [PtR2S2]2+ (R = Ph, Me; S = Me2SO, Me2S) are all positive. The overall mechanistic picture has been taken as the ¢rst clear-cut evidence for the operation of a D mechanism involving a 3 -coordinate 14 -electron intermediate for simple ligand substitution on square-planar complexes (206) (Table XV (196,198,200,202,206^211)). Deeth et al. Their calculations strongly support that H2O exchange on these complexes proceeds through an a-activation mechanism, in full agreement with experimental assignments.

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Advances in Inorganic Chemistry: Inorganic Reaction Mechanisms (AIC) (Advances in Inorganic Chemistry) by Colin D. Hubbard Rudi Van Eldik

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